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pH Adjustment

pH is a measure of the degree of acidity and basicity of a solution. More exactly, it is the measurement (negative logarithm) of hydrogen ion concentration [H+]. The scale ranges from 0 (most acidic) to 14 (most basic). The term pH refers to “pondus hydrogenii” or power of hydrogen

phadjust

Because pH is simply another means of referring to the hydrogen ion concentration, acidic and basic solutions can be distinguished on the basis of pH values:

pH < 7 pH = 7 pH > 7 Acidic solution
Neutral solution
Basic solution

Wastewater Discharge Requirements

Neutralization of wastewater that is highly acidic (low pH) or highly basic (high pH) is required for discharge to municipal sewer systems or to rivers and to streams. The allowable pH range for discharge is generally 6 to 9 standard units (S.U.) but can be 5.0 to 11.0 depending on the source of discharge. There are four main reasons to control the pH in wastewater:

  • Protect human health and the environment; fish and other living organisms in rivers and streams.
  • Protect the wastewater infrastructure from corrosion, especially from acidic wastewater.
  • Protect the biological treatment process incorporated at most publicly owed treatment works (POTW).
  • Many pretreatment systems require that the pH be adjusted as an initial step in the treatment process, such as:

Sources

There are many types of industries with multiple sources of wastewater that, if discharged untreated, will violate pH requirements. Acids and bases are used throughout plant production and in cleaning operations.

Treatment

Wastewater with a low pH is generally neutralized using sodium hydroxide (NaOH), lime (CaO), magnesium hydroxide (Mg(OH)2), or calcium hydroxide (Ca(OH)2). Wastewater with a high pH is generally neutralized with sulfuric acid (H2SO4), hydrochloric acid (HC1), or carbon dioxide (CO2). The most common chemicals used are H2SO4 and NaOH.

Neutralization can be accomplished by batch treatment or continuous flow processes. Batch treatment is usually for lower flow volumes.

Most systems are continuous flow type systems consisting of one or two neutralization tanks, depending on the flow rate and magnitude of pH swings. With some systems, the pH must be raised or lowered for other removal processes to function properly, and then the pH adjusted back prior to discharge. A simple single tank continuous flow pH neutralization process is shown in the diagram.

A pH sensor, located in the tank, measures the pH and, if necessary, the pH indicator-controller system activates the appropriate metering pump, which automatically doses acid or caustic based on the pH of the wastewater.

“Anyone who can solve the problems of water will be worthy of two Nobel prizes – one for peace and one for science.” – John F. Kennedy